OLIN CORPORATION -- HTH DRY CHLORINE,GRANULAR,70% CHLORINE -- 6810-00-242-4770
===================== Product Identification ===================== Product ID:HTH DRY CHLORINE,GRANULAR,70% CHLORINE MSDS Date:01/01/1985 FSC:6810 NIIN:00-242-4770 === Responsible Party === Company Name:OLIN CORPORATION Address:120 LONG RIDGE RD City:STAMFORD State:CT ZIP:06904 Country:US CAGE:0G578 === Contractor Identification === Company Name:OLIN CORP CHEMICALS GROUP Address:120 LONG RIDGE RD City:STAMFORD State:CT ZIP:06904 Country:US Phone:203-356-3449,CHEMTREC 800-242-9300 CAGE:53084 Company Name:OLIN CORPORATION Address:120 LONG RIDGE ROAD City:STAMFORD State:CT ZIP:06904-1355 Country:US Phone:203-356-3449 CAGE:0G578 ============= Composition/Information on Ingredients ============= Ingred Name:STRONG OXIDING AGENT,CALCIUM HYPOCHLORITE,70% AVAILABLE CHLORINE,HTH. CAS:22464-76-2 RTECS #:NH3485500 Fraction by Wt: 70.0% ACGIH TLV:N.A ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATION OF EYES,SKIN AND MUCOUS MEMBRANES.MAY PRODUCE SEVERE CHEMICAL BURNS.HARMFUL IF SWALLOWED. ======================= First Aid Measures ======================= First Aid:ANTIDOTE:EXTERNAL-FLOOD SIN OR EYES WITH WATER FOR 15 MINUTES.IF IRRITATION TO SKIN PERSISTS,GET MEDICAL ATTENTION.FOR EYES-CALL DOCTOR.INTERNAL-DRINK LARGE QUANTITIES OF WATER OR MILK.FOLLOW WITH MIL K OR MAGNESIA,VEGETABLE OIL,OR BEATEN EGGS. ===================== Fire Fighting Measures ===================== Flash Point:N.A Extinguishing Media:WATER,PREFERABLE SPRAY. Fire Fighting Procedures:DRENCH WITH WATER AND COOL THE SURROUNDING DRUMS AND AREA. Unusual Fire/Explosion Hazard:HTH IS NOT A COMBUSTIBLE MATERIAL.CONTAMINATION MAY RESULT IN GREAT FIRE.CLOSED DRUM MAY BURST. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH REDUCING AGENTS SUCH AS HYPO,BISULFITES OR FERROUS SALTS.BISULFITES OR FERROUS SALTS NEED ADDITIONAL PROMOTER OF SOME 3M-H*2SO*4 FOR RAPID REACTION.TRANSFER THE SLURRY INTO LARGE CONTAINER OF WATER,NEUTRALIZE WITH SODA ASH.DISPOSE TO DRAIN ====================== Handling and Storage ====================== Handling and Storage Precautions:MIX ONLY WITH WATER.HTH IS A POWERFUL OXIDANT.KEEP AWAY FROM COMBUSTIBLE ORGANIC MATERIAL.DO NOT CONTAMINATE WITH ANY FOREIGN MATERIAL CAUSES FIRE . Other Precautions:DURING A FIRE,IF DRUM OR CONTAINER IS CLOSED PRESSURE CAN BLOW OFF LID OR RUPTURE OF CONTAINER.PROTECT AGAINST PHYSICAL DAMAGE.STORE IN A COOL,WELL VENTILATED PLACE.KEEP AWAY FROM ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR OR DUST MASK. Ventilation:MECHANICAL OR LOCAL EXHAUST AS NEEDED. Protective Gloves:NEOPRENE Eye Protection:GOGGLES Other Protective Equipment:PROTECTIVE OUTWEAR. Supplemental Safety and Health THIS PRODUCT CONTAINS 70% AVAILABLE CHLORINE ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:N.A Evaporation Rate & Reference:N.A Solubility in Water:APPRECIABLE Appearance and Odor:FREE FLOWING,WHITE,GRANULAR,SLIGHT CHLORINOUS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HOUSEHOLD SOAP,PAINT PRODUCTS,SOLVENTS,ACIDS,VINEGAR,DRINKS. Stability Condition to Avoid:HEATING ABOVE 350F,AS IT DECOMPOSES RAPIDLY EVOLVES OXYGEN Hazardous Decomposition Products:DECOMPOSES RAPIDLY WITH CHEMICAL FUMING EVOLVES OXYGEN,HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:USE VAST VOLUME OF CONCENTRATED SOLUTION OF REDUCING AGENT(BISULFITES OR FERROUS SALTS WITH 3M-H*2SO*4 OR HYPO).NEUTRALIZE WITH SODA ASH OR DILUTE HCL.DRAIN INTO APLROVED DISPOSAL AREA WITH ABUNDANT W ATER Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.